TE1268 Tellurium Tetrachloride (TeCl4) Powder (CAS No.10026-07-0)

SECTION 1. IDENTIFICATION

Product Name: Tellurium Tetrachloride

CAS #: 10026-07-0

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: [email protected]

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

GHS05 Corrosion

Skin Corr. 1B H314 Causes severe skin burns and eye damage.

Eye Dam. 1 H318 Causes serious eye damage.

GHS label elements

The substance is classified and labeled according to the Globally Harmonized System (GHS).

Hazard

GHS05

Signal word Danger

Hazard-determining components of labeling:

tellurium tetrachloride

Hazard statements

H314 Causes severe skin burns and eye damage.

Precautionary statements

P101 If medical advice is needed, have product container or label at hand.

P102 Keep out of reach of children.P103 Read label before use.

P231 Handle under inert gas.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.

Rinse skin

with water/shower.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if

present and easy to do. Continue rinsing.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P422 Store contents under inert gas.

P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.

Classification system:

NFPA ratings (scale 0 - 4)

4

0

0

Health = 4

Fire = 0

Reactivity = 0

HMIS-ratings (scale 0 - 4)

HEALTH

FIRE

REACTIVITY

4

0

0

Health = 4

Fire = 0

Reactivity = 0

Other hazards

Results of PBT and vPvB assessment

PBT: N/A

vPvB: N/A

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances

CAS # / Substance Name

10026-07-0 tellurium tetrachloride

Identification number(s)

EC number: 233-055-6

SECTION 4. FIRST AID MEASURES

Description of first aid measures

General information: Immediately remove any clothing soiled by the product.

If inhaled: In case of unconsciousness place patient stably in side position for transportation.

In case of skin contact: Immediately wash with soap and water; rinse thoroughly.

In case of eye contact: Rinse opened eye for several minutes under running water. Consult a

physician.If swallowed: Drink copious amounts of water and provide fresh air. Immediately call a doctor.

Most important symptoms and effects, both acute and delayed:

No data available

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing agents:

CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

Special hazards arising from the substance or mixture No data available

Advice for firefighters

Protective equipment: No special measures required.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Keep unprotected persons away.

Environmental precautions: No special measures required.

Methods and materials for containment and cleanup:

Use neutralizing agent.

Dispose contaminated material as waste according to item 13.

Ensure adequate ventilation.

Reference to other sections

See Section 7 for information on safe handling.

See Section 8 for information on personal protection equipment.

See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling Thorough dedusting.

Information about protection against explosions and fires: No special measures required.

Conditions for safe storage, including any incompatibilities:

Requirements to be met by storerooms and receptacles: No special requirements.

Information about storage in one common storage facility: Not required.

Further information about storage conditions: Keep receptacle tightly sealed.

Specific end use(s) No data available

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems: No further data; see item 7.

Control parameters

Components with limit values that require monitoring at the workplace:

10026-07-0 tellurium tetrachloride

PEL Long-term value: 0.1 mg/m

3

as TeREL Long-term value: 0.1 mg/m

3

as Te

TLV Long-term value: 0.1 mg/m

3

as Te

Additional information: The lists that were valid during the creation were used as basis.

Exposure controls

Personal protective equipment:

General protective and hygienic measures:

Keep away from foodstuffs, beverages and feed.

Immediately remove all soiled and contaminated clothing.

Wash hands before breaks and at the end of work.

Avoid contact with the eyes.

Avoid contact with the eyes and skin.

Breathing equipment: Not required.

Protection of hands:

`SProtective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the

preparation.

Due to missing tests no recommendation to the glove material can be given for the product/ the

preparation/ the

chemical mixture.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the

degradation

Material of gloves

The selection of the suitable gloves does not only depend on the material, but also on further marks of

quality and

varies from manufacturer to manufacturer.

Penetration time of glove material

The exact break through time has to be found out by the manufacturer of the protective gloves and

has to be

observed.

Eye protection:

`RTightly sealed goggles

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance:

Form: Powder

Color: Whitish

Odor: Pungent

Odor threshold: No data available.

pH: N/A

Melting point/Melting range: 224 °C (435 °F)

Boiling point/Boiling range: 380 °C (716 °F)

Flash point: N/A

Flammability (solid, gas): Product is not flammable.

Ignition temperature:

Decomposition temperature: No data available.

Autoignition: No data available.

Danger of explosion: Product does not present an explosion hazard.

Explosion limits:Lower: No data available.

Upper: No data available.

Vapor pressure: no data hPa

Density at 20 °C (68 °F): 3.26 g/cm

3

(27.205 lbs/gal)

Relative density No data available.

Vapor density N/A

Evaporation rate N/A

Solubility in / Miscibility with

Water: Insoluble.

Partition coefficient (n-octanol/water): No data available.

Viscosity:

Dynamic: N/A

Kinematic: N/A

Organic solvents: 0.0 %

Solids content: 100.0 %

Other information No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity

Chemical stability

Thermal decomposition / conditions to be avoided: No decomposition if used according to

specifications.

Possibility of hazardous reactions No dangerous reactions known.

Conditions to avoid No data available

Incompatible materials: No data available

Hazardous decomposition products: No dangerous decomposition products known.

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity:

Primary irritant effect:

on the skin: Strong caustic effect on skin and mucous membranes.

on the eye:

Strong caustic effect.

Strong irritant with the danger of severe eye injury.

Sensitization: No sensitizing effects known.

Additional toxicological information:

Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of

esophagus

and stomach.

Carcinogenic categories

IARC (International Agency for Research on Cancer)

Substance is not listed.

NTP (National Toxicology Program)

Substance is not listed.

OSHA-Ca (Occupational Safety & Health Administration)

Substance is not listed.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity

Aquatic toxicity: No data available

Persistence and degradability No data available

Bioaccumulative potential No data available

Mobility in soil No data available

Additional ecological information: Must not reach bodies of water or drainage ditch undiluted or

unneutralized.

Results of PBT and vPvB assessment

PBT: N/A

vPvB: N/A

Other adverse effects No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Recommendation:

Must not be disposed of together with household garbage. Do not allow product to enter drains,

sewage systems, or other water courses system.

Uncleaned packagings:

Recommendation: Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

UN-Number

DOT, IMDG, IATA UN1759

UN proper shipping name

DOT Corrosive solids, n.o.s.

IMDG, IATA CORROSIVE SOLID, N.O.S.

Transport hazard class(es)

DOT

Class 8 Corrosive substances

Label 8

IMDG, IATA

Class 8 Corrosive substances

Label 8

Packing group

DOT, IMDG, IATA II

Environmental hazards:

Marine pollutant: No

Special precautions for user Warning: Corrosive substances

Danger code (Kemler): 60

EMS Number: F-A,S-B

Transport in bulk according to Annex II of

MARPOL73/78 and the IBC Code N/A

Transport/Additional information:

DOT

Quantity limitations On passenger aircraft/rail: 15 kg

On cargo aircraft only: 50 kgIMDG

Limited quantities (LQ) 1 kg

Excepted quantities (EQ) Code: E2

Maximum net quantity per inner packaging: 30 g

Maximum net quantity per outer packaging: 500 g

UN "Model Regulation": UN1759, Corrosive solids, n.o.s., 8, II

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture

Sara

Section 355 (extremely hazardous substances):

Substance is not listed.

Section 313 (Specific toxic chemical listings):

Substance is not listed.

TSCA (Toxic Substances Control Act):

Substance is listed.

Proposition 65

Chemicals known to cause cancer:

Substance is not listed.

Chemicals known to cause reproductive toxicity for females:

Substance is not listed.

Chemicals known to cause reproductive toxicity for males:

Substance is not listed.

Chemicals known to cause developmental toxicity:

Substance is not listed.

Carcinogenic categories

EPA (Environmental Protection Agency)

Substance is not listed.

TLV (Threshold Limit Value established by ACGIH)

Substance is not listed.

NIOSH-Ca (National Institute for Occupational Safety and Health)

Substance is not listed.

GHS label elements

The substance is classified and labeled according to the Globally Harmonized System (GHS).

Hazard pictograms

~?GHS05

Signal word Danger

Hazard-determining components of labeling:

tellurium tetrachloride

Hazard statements

H314 Causes severe skin burns and eye damage.

Precautionary statements

P101 If medical advice is needed, have product container or label at hand.

P102 Keep out of reach of children.

P103 Read label before use.

P231 Handle under inert gas.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.

Rinse skin

with water/shower.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if

present and easy to do. Continue rinsing.P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P422 Store contents under inert gas.

P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.

Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.