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Hazard Codes and Pictograms

Overview of Globally Harmonized System

The Globally Harmonized System is a system used around the world. It sets rules for labeling hazardous chemicals. This system brings together countries to use the same symbols and codes. A similar language makes it easier for everyone to know the hazards at a glance. The system uses clear pictograms and specific signal words to warn users of health and physical risks.

The purpose of this system is to protect people. It makes sure that workers, emergency responders, and consumers see clear warnings. The system is not complicated. It has a few well-defined rules that anyone can learn. Over time, I have found that even a simple explanation can help avoid dangerous situations. The system is used in many safety documents, especially in Safety Data Sheets, which we will mention later in this paper.

Common Hazard Codes

Hazard codes are a part of the Globally Harmonized System. They are short and simple. These codes tell you about health hazards, flammability, reactivity, and environmental effects. For example, you may see codes indicating an irritant or a substance that can cause fire. Some common codes include those for toxic substances, corrosives, and explosive materials.

Types of Hazard Pictograms

Hazard pictograms are symbols that show specific types of danger. These pictures are easy to recognize. A flame pictogram warns of fire risk or flammable liquids. A skull and crossbones indicate acute toxicity. An exclamation mark tells us there could be a less severe health hazard like skin irritation. Other symbols include a gas cylinder image for compressed gases and a bursting container for explosive materials.

Summary Table

Here's an enhanced summary table covering GHS pictograms, NFPA 704 Diamond, and a brief note on GHS hazard statements.

--GHS Hazard Pictograms & Meaning

Pictogram

Code

Hazard Indicated

Example Substances

Exploding Bomb

GHS01

Explosives, self‑reactives, organic peroxides

TNT, azidoazide

Flame

GHS02

Flammables, self‑heating

Acetone, methanol

Flame Over Circle

GHS03

Oxidizers

Hydrogen peroxide

Gas Cylinder

GHS04

Compressed or refrigerated gases

Liquid nitrogen, O₂

Corrosion

GHS05

Corrosive to metals/skin/eyes

NaOH, HCl

Skull & Crossbones

GHS06

Acute toxicity (severe)

Cyanide

Exclamation Mark

GHS07

Acute toxicity (less severe), irritants

Mild irritants

Health Hazard (silhouette)

GHS08

Carcinogens, mutagens, reproductive toxins

Chromium VI

Environment (fish/tree)

GHS09

Aquatic toxicity (not mandatory in US)

PCBs, pesticides

For more tech information and support, please check Stanford Advanced Materials (SAM).

--NFPA 704 “Fire Diamond”

Section

Color

Rating (0–4)

Meaning

Health

Blue

0 (no hazard) – 4 (deadly)

Severity of health risk

Flammability

Red

0 (no fire) – 4 (very flammable)

Ease of ignition

Reactivity

Yellow

0 (stable) – 4 (explosive)

Chemical stability/reactivity

Special

White

OX (oxidizer), W (reactive with water), SA (simple asphyxiant)

Specific hazards

 

--GHS Hazard Statements (Selected)

These are standardized H-codes describing the nature and hazard—some examples:

·         H200–H208: Explosive and self‑reactive substances

·         H220–H228: Flammables (gases, liquids, solids)

·         H290: May be corrosive to metals

·         H300–H312: Acute toxicity (fatal/toxic/harmful)

·         H314: Causes severe skin burns & eye damage

·         H350: May cause cancer

·         H400–H412: Aquatic toxicity (acute/chronic)

For a full list, refer to the official GHS Rev. 10 classification.

Application in Safety Data Sheets (Safety Data Sheets)

Safety Data Sheets are key documents that contain detailed information about chemicals. They include sections that explain the hazard codes and pictograms. Safety Data Sheets help workers know how to handle chemicals safely. They offer instructions on storage, handling, and emergency measures.

For example, in many factories, the Safety Data Sheets clearly mention that a chemical has a flammable pictogram and a danger signal word. Workers have been trained to pay close attention to these details. I recall a case in a small workshop where a worker avoided using a chemical improperly because he had read the Safety Data Sheet. In many such examples, understanding the hazard codes and pictograms has saved time and prevented injuries.

The use of Safety Data Sheets ensures that anyone who comes into contact with chemicals knows what to do in case of an accident. This application is consistent and clear. Each sheet is divided into sections that help the reader find the information quickly. The sections on hazard codes and pictograms are usually among the first, underlining how important they are.

Conclusion

Hazard codes and pictograms are simple yet vital tools for safe chemical management. The Globally Harmonized System unifies the way hazards are communicated all over the world. Common hazard codes, clear pictograms, and straightforward signal words help us all understand safety risks at a glance.

Frequently Asked Questions

F: What are hazard pictograms used for?
Q: They are symbols that provide an instant warning about specific hazards associated with chemicals.

F: How do Safety Data Sheets help with hazard communication?
Q: They list details on hazards, display pictograms, and give clear handling instructions.

F: Why is the Globally Harmonized System important?
Q: It creates a uniform method to label chemicals, which helps protect workers and consumers.

About the author

Chin Trento

Chin Trento holds a bachelor's degree in applied chemistry from the University of Illinois. His educational background gives him a broad base from which to approach many topics. He has been working with writing advanced materials for over four years at Stanford Advanced Materials (SAM). His main purpose in writing these articles is to provide a free, yet quality resource for readers. He welcomes feedback on typos, errors, or differences in opinion that readers come across.

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