SECTION 1. IDENTIFICATION
Product Name: Sulfur Powder
CAS #: 7704-34-9
Relevant identified uses of the substance: Scientific research and development
Supplier details:
Stanford Advanced Materials
E-mail: [email protected]
Tel: (949) 407-8904
Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.
SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS02 Flame
Flam. Sol. 1 H228 Flammable solid.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Hazards not otherwise classified
No data available.
GHS label elements
The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS02
GHS07
Signal word
Danger
Hazard statements
H228 Flammable solid.H315 Causes skin irritation.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P362 Take off contaminated clothing and wash before reuse.
P321 Specific treatment (see on this label).
WHMIS classification
B4 - Flammable solid
D2B - Toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH 1
FIRE 2
REACTIVITY 0
Health (acute effects) = 1
Flammability = 2
Physical Hazard = 0
Other hazards
Results of PBT and vPvB assessment:
PBT:
N/A.
vPvB:
N/A.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
CAS No. / Substance Name: 7704-34-9 Sulphur
Identification number(s):
EC number: 231-722-6
Index number: 016-094-00-1
SECTION 4. FIRST AID MEASURES
Description of first aid measures
If inhaled:
Supply fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No information available.Indication of any immediate medical attention and special treatment needed
No information available.
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol
resistant foam.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Sulfur oxides (SOx)
Hydrogen sulfide
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
Environmental precautions:
Do not allow material to be released to the environment without official permits.
Methods and material for containment and cleanup:
Keep away from ignition sources.
Ensure adequate ventilation.
Prevention of secondary hazards:
Keep away from ignition sources.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure adequate ventilation.
Information about protection against explosions and fires:
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Information about storage in one common storage facility:Store away from oxidizing agents.
Store away from halocarbons.
Do not store with interhalogens.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s)
No information available.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average
face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that should be
monitored at the workplace.
Additional information:
No data
Exposure controls
Personal protective equipment
Follow typical general protective and industrial hygiene measures for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Recommended filter device for short term use:
Use a respirator with type N95 (USA) or PE (EN 143) cartridges as a backup to engineering controls.
Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only
use equipment tested and approved under appropriate government standards.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
Suitability of gloves should be determined both by material and quality, the latter of which may vary by
manufacturer.
Material of gloves
Nitrile rubber, NBR
Penetration time of glove material (in minutes)
480
Glove thickness
0.11 mm
Eye protection:
Safety glasses
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance:Form:
Various forms (powder/flake/crystalline/beads, etc.)
Color:
Pale yellow
Odor:
Weak
Odor threshold:
No data available.
pH:
N/A.
Melting point/range:
115.21 °C (239 °F)
Boiling point/range:
444.6 °C (832 °F)
Sublimation temperature / start:
No data available.
Flash point:
> 999 °C (> 1830 °F)
Flammability (solid, gas):
Highly flammable.
Ignition temperature:
248 °C (478 °F)
Decomposition temperature:
No data available.
Auto igniting:
No data available.
Danger of explosion:
No data available.
Explosion limits:
Lower:
3.3 Vol %
Upper:
46 Vol %
Vapor pressure:
N/A.
Density at 20 °C (68 °F):
2.07 g/cm³ (17.274 lbs/gal)
Relative density
No data available.
Vapor density
N/A.
Evaporation rate
N/A.
Solubility in Water (H
2
O):
Insoluble
Partition coefficient (n-octanol/water):
No data available.
Viscosity:
Dynamic:
N/A.
Kinematic:
N/A.
Other information
No information available.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
No data available.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Reacts with strong oxidizing agents
Conditions to avoid
No information available.
Incompatible materials:
Oxidizing agents
Halocarbons
Interhalogens
Hazardous decomposition products:
Sulfur oxides (SOx)
Hydrogen sulfide
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for
components in this product.
LD/LC50 values that are relevant for classification:
Inhalative LC50 1660 mg/m3 (mam)
Skin irritation or corrosion:
Causes skin irritation.
Eye irritation or corrosion:
May cause irritation
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
N/A
Carcinogenicity:
No classification data on carcinogenic properties of this material is available from the EPA, IARC,
NTP, OSHA or ACGIH.
Reproductive toxicity:
N/A
Specific target organ system toxicity - repeated exposure:
N/A
Specific target organ system toxicity - single exposure:
N/A
Aspiration hazard:
N/A
Subacute to chronic toxicity:
N/A
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.Carcinogenic categories
OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity:
No information available.
Persistence and degradability:
No information available.
Bioaccumulative potential:
No information available.
Mobility in soil:
No information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without official permits.
Avoid transfer into the environment.
Results of PBT and vPvB assessment:
PBT:
N/A.
vPvB:
N/A.
Other adverse effects
No information available.
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation:
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
UN-Number
DOT, IMDG, IATA
UN1350
UN proper shipping name
DOT
Sulfur
IMDG, IATA
SULPHUR
Transport hazard class(es)
DOT
Class
4.1 Flammable solids, self-reactive substances and solid desensitised explosives.Label
4.1
Class
4.1 (F3) Flammable solids, self-reactive substances and solid desensitised explosives
Label4.1
IMDG, IATA
Class
4.1 Flammable solids, self-reactive substances and solid desensitised explosives.
Label
4.1
Packing group
DOT, IMDG, IATA
III
Environmental hazards:
N/A.
Special precautions for user
Warning: Flammable solids, self-reactive substances and solid desensitised explosives
EMS Number:
F-A,S-G
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N/A.
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
UN "Model Regulation":
UN1350, Sulfur, 4.1, III
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements
The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS02
GHS07
Signal word
Danger
Hazard statements
H228 Flammable solid.
H315 Causes skin irritation.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P362 Take off contaminated clothing and wash before reuse.
P321 Specific treatment (see on this label).
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic
Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No
1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
SECTION 16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is
believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the
properties of the product.
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